TWO-STEP SYNTHESIS AND FORMATION MECHANISM FOR LACUOS NANO-SIZED AGGLOMERATES
Keywords:
lanthanide copper oxychalcogenide, two-step synthesis, co-precipitation, reduction
Abstract
We have developed a two-step synthesis method to obtain pure LaCuOS nano-sized agglomerates using La(NO3)3·6H2O, CuSO4·5H2O and NH3·H2O as the starting materials. The result shows that the precursor can be converted into La2O2SO4, La2(SO4)3 and CuO phases at 800 °C for 2 h in air, which was then converted into a pure LaCuOS phase by a reduction at 800 °C for 5 h in a flowing argon and hydrogen atmosphere. The as prepared LaCuOS nano-aggregates have poor dispersion and a wide size distribution range (50–100 nm).
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6 H. Kamioka, H. Hiramatsu, H. Ohta, M. Hirano, App. Phys. Lett., 84(6), 879 (2004).
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12 K. Takase，K. Sato，O. Shoji，Y. Takahashi，Y. Takano，K. Sekizawa，Y. Kuroiwa，M. Goto, App. Phys. Lett., 90(16), 161916 (2007).
13 K. Ueda, S. Inoue, H. Hosono, N. Sarukura, M. Hirano, App. Phys. Lett., 78(16), 2333 (2001).
14 A. Renaud, L. Cario, Y. Pellegrin, E. Blart, M. Boujtita, F. Odobel, S. Jobic, RSC Adv., 5(74), 60148 (2015)
15 H. Yanagi , M. Kikuchi, K. Kim, H. Hiramatsu, T. Kamiya, M. Hirano, H. Hosono, Org. Electron. 9(5), 890 (2008)
16 M. Palazzi, C. R. Acad. Sci. Paris, 292, 789 (1981).
17 Y. Goto, M. Tanaki, Y. Okusa, T. Shibuya, K. Yasuoka, M. Matoba, Y. Kamihara, App. Phys. Lett., 105(2), 022104 (2014).
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20 Y. Takano, C. Ogawa, Y. Miyahara, H. Ozaki, K. Sekizawa, J. Alloys Compd, 249(1-2), 221 (1997).
21 H. Hiramatsu, K. Ueda, H. Ohta, M. Orita, M. Hirano, H. Hosono, App. Phys. Lett., 81(4), 598 (2002).
22 H. Hiramatsu, K. Ueda, H. Ohta, M. Hirano, T. Kamiya, H. Hosono, Thin Solid Films, 445(2), 304 (2003).
23 H. Hiramatsu, K. ueda, K. takafuji, H. ohta M. Hirano, T. kamiya, H. hosono, Appl. Phys. A, 79, 1517 (2004).
24 N.D. Zhang, D.W. Shi, X.X. Liu, A. Annadi, B.S. Tang,T.J. Huang, H. Gong, Appl. Mater. Today, 13, 15 (2018).
25 J.B. Lian, N.N. Li, H.L. Wang, Y. Su, G.M. Zhang, F. Liu, Cera. Int., 42(9), 11473 (2016).
26 L.H. Lee, Prog. Colloid Polym. Sci., 82, 337 (1990).
27 K. Huang, J.J. Wang, D.F. Wu, S. Lin, RSC Adv., 5(11), 8455 (2015).
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Published
2023-07-29
How to Cite
1.
Li X, Li Q, Ma Z, Sun Y. TWO-STEP SYNTHESIS AND FORMATION MECHANISM FOR LACUOS NANO-SIZED AGGLOMERATES. MatTech [Internet]. 2023Jul.29 [cited 2025Nov.18];57(4):359–366. Available from: https://mater-tehnol.si/index.php/MatTech/article/view/879
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