ROLE OF OLIVINE AGGREGATE IN LIME AND CEMENT MORTARS FOR THE SEQUESTRATION OF ATMOSPHERIC CO2

  • Sriram Pradeep Saridhe VR Siddhartha Engineering College, Department of Civil Engineering, Vijayawada, Andhra Pradesh, India
  • M. Hareesh School of Civil Engineering, Vellore Institute of Technology, Vellore, Tamil Nadu, India
  • Shanmuga Priya T School of Civil Engineering, Vellore Institute of Technology, Vellore, Tamil Nadu, India
  • Thirumalini Selvaraj CO2 Research & Green technologies Centre, Vellore Institute of Technology, Vellore, Tamil Nadu, India
Keywords: carbon capture, carbon sequestration, olivine aggregate

Abstract

Construction industry is majorly criticised due to a great liberation of carbon dioxide (CO2) into the atmosphere. Researchers have identified various techniques to capture the atmospheric CO2. Nevertheless, the recognised methods have both merits as well as demerits. Thus, scientific communities are working on simple and easily exhibited ways of capturing atmospheric CO2. One such technique is the conversion of gaseous CO2 into stable calcium/magnesium carbonates. The present study was conducted to identify the carbon-capturing efficiency of olivine aggregate in cement and lime mortars. Olivine aggregate has a tendency to change its mineral structure under alkaline environment and it is able to interact with atmospheric CO2 to form a stable carbonate. Analytical techniques (XRD, TGA) were conducted to elucidate the formation of hydrated phases formed in both lime and cement mortars. The study concluded that the addition of olivine sequestered atmospheric CO2 and converted it into magnesium carbonate. Out of the lime and cement mortar, lime mortar captured a greater amount of CO2 and produced stable compounds.

References

1. P. K. Mehta, P. J. Monteiro, Concrete: microstructure, properties, and materials, McGraw-Hill Education, 2014

2. R. M. Cuéllar-Franca, A. Azapagic, Carbon capture, storage and utilisation technologies: A critical analysis and comparison of their life cycle environmental impacts, Journal of CO2 Utilization, 9 (2015), 82–102, doi:10.1016/j.jcou.2014.12.001

3. K. M. K. Yu, I. Curcic, J. Gabriel S. C. E. Tsang, Recent advances in CO2 capture and utilization, ChemSusChem: Chemistry & Sustainability, Energy & Materials, 1 (2008) 11, 893–899, doi:10.1002/cssc.200800169

4. J. Li., Mechanical activation of ultramafic mine waste materials for enhanced mineral carbonation, The University of British Columbia, 2017, doi:10.14288/1.0343400

5. S. Mindess, Sustainability of concrete, In: Developments in the Formulation and Reinforcement of Concrete, 2019, 3–17, doi:10.1016/B978-0-08-102616-8.00001-0

6. A. Naqi, J. G. Jang, Recent progress in green cement technology utilizing low-carbon emission fuels and raw materials: A review, Sustainability, 11 (2019) 2, 537, doi:10.3390/su11020537

7. L. K. Turner, F. G. Collins, Carbon dioxide equivalent (CO2) emissions: A comparison between geopolymer and OPC cement concrete, Construction and Building Materials, 43 (2013), 125–130, doi:10.1016/j.conbuildmat.2013.01.023

8. P. B. Cachim, Mechanical properties of brick aggregate concrete, Construction and Building Materials, 23 (2009) 3, 1292–1297, doi:10.1016/j.conbuildmat.2008.07.023

9. R. M. Lawrence, T. J. Mays, S. P. Rigby, P. Walker, D. D’Ayala, Effects of carbonation on the pore structure of non-hydraulic lime mortars, Cement and Concrete Research, 37 (2007) 7, 1059–1069, doi:10.1016/j.cemconres.2007.04.011

10. M. H. Fasihnikoutalab, A. Asadi, B. K. Huat, P. Westgate, R. J. Ball, S. Pourakbar, Laboratory-scale model of carbon dioxide deposition for soil stabilisation, Journal of Rock Mechanics and Geotechnical Engineering, 8 (2016) 2, 178–186, doi:10.1016/j.jrmge.2015.11.001

11. P. Westgate, R. J. Ball, K. Paine, Olivine as a reactive aggregate in lime mortars, Construction and Building Materials, 195 (2019), 115–126, doi:10.1016/j.conbuildmat.2018.11.062

12. ISO 712: 1984 – Specification for building limes, New Delhi, India, Bureau of Indian Standards

13. ISO 2386 (Part I): 1963 – Method of test for aggregate and concrete-particle size and shape, New Delhi, India, Bureau of Indian Standards

14. ISO 6932 (Part VII): 1973 – Methods of tests for building limes, Determination of compressive and transverse strengths, New Delhi, India, Bureau of Indian Standards

15. ISO 2550: 1981 – Code of practice for preparation of masonry mortars, New Delhi, India, Bureau of Indian Standards

16. S. P. Saridhe, T. Selvaraj, Reporting the ancient green construction technology of limecrete slabs adopted in Udaipur, Rajasthan, Journal of Cleaner Production, 279 (2021), 123682, doi:10.1016/j.jclepro. 2020.123682

17. M. H. Fasihnikoutalab, P. Westgate, B. B. K. Huat, A. Asadi, R. J. Ball, H. Nahazanan, P. Singh, New insights into potential capacity of olivine in ground improvement, Electron. J. Geotech. Eng., 20 (2015), 2137–2148

18. G. Cultrone, E. Sebastián, M. O. Huertas, Forced and natural carbonation of lime-based mortars with and without additives: Mineralogical and textural changes, Cement and Concrete Research, 35 (2005) 12, 2278–2289, doi:10.1016/j.cemconres.2004.12.012

19. M. Singh, S. V. Kumar, S. A. Waghmare, P. D. Sabale, Aragonite–vaterite–calcite: Polymorphs of CaCO3 in 7th century CE lime plasters of Alampur group of temples, India, Construction and Building Materials, 112 (2016), 386–397, doi:10.1016/j.conbuildmat. 2016.02.191

20. Ö. Cizer, K. Van Balen, D. A. Van Gemert, Competition between hydration and carbonation in hydraulic lime and lime-pozzolana mortars, Advanced Materials Research, 133 (2010), 241–246, doi:10.4028/www.scientific.net/AMR.133-134.241

Published
2023-03-30
How to Cite
1.
Saridhe SP, M. Hareesh, Shanmuga Priya T, Selvaraj T. ROLE OF OLIVINE AGGREGATE IN LIME AND CEMENT MORTARS FOR THE SEQUESTRATION OF ATMOSPHERIC CO2. MatTech [Internet]. 2023Mar.30 [cited 2026Sep.8];57(2):135–140. Available from: https://mater-tehnol.si/index.php/MatTech/article/view/719