MECHANICAL BEHAVIOUR OF INFLORESCENCE/GLASS-FIBRE-REINFORCED HYBRID EPOXY COMPOSITES
Abstract
The biodegradability and environmental friendliness of natural fibres makes them suitable for implementation in a circular economy. As a result, several natural fibres and processing methods have evolved. The hydrophilic nature of ligno cellulose fibrils restricts the effective adhesion at the interface of fibre and matrix. The hybridization of natural fibres with synthetic fibres leads to promising characteristics of the resulting composite materials. This paper deals with the hybridization of conventional glass fibre and natural fibre extracted from coconut inflorescence. The effect of hybridization on the tensile and flexural strengths of surface-modified inflorescence fibre with glass fibres was investigated. The composites were fabricated using a hand-layup technique by varying the inflorescence fibre and glass-fibre reinforcement composition by (5, 10, 15 and 20) %. A notable improvement in the tensile and flexural strengths of 193.65 MPa and 240.69 MPa was observed for 85 % of glass and 15 % of benzoyl-chloride-modified inflorescence-fibre-reinforced hybrid composites. The elimination of amorphous constituents in the inflorescence fibres was checked by XRD and FTIR analyses. A surface-morphology analysis of unmodified and benzoyl-chloride-modified inflorescence fibres revealed pores and cavity formation on the fibril walls. These composites with superior mechanical properties can be an alternative to synthetic fibre composites and ensure the implementation of a circular economy and sustainable manufacturing.
References
2. Senthamaraikannan, P., S.S. Saravanakumar, M.R. Sanjay, Mohammad Jawaid, and Suchart Siengchin. “Physico-Chemical and Thermal Properties of Untreated and Treated Acacia Planifrons Bark Fibers for Composite Reinforcement.” Materials Letters 240 (April 2019): 221–24. https://doi.org/10.1016/j.matlet.2019.01.024.
3. Margem, Jean Igor, Vinicius Alves Gomes, Frederico Muylaert Margem, Carolina Gomes Dias Ribeiro, Fabio Oliveira Braga, and Sergio Neves Monteiro. “Flexural Behavior of Epoxy Matrix Composites Reinforced with Malva Fiber.” Materials Research 18, no. suppl 2 (November 17, 2015): 114–20. https://doi.org/10.1590/1516-1439.359514.
4. Wang, Zhihao, Lemma Dadi Bekele, Yue Qiu, Yifan Dai, Shiqiang Zhu, Surendra Sarsaiya, and Jishuang Chen. “Preparation and Characterization of Coffee Hull Fiber for Reinforcing Application in Thermoplastic Composites.” Bioengineered 10, no. 1 (January 1, 2019): 397–408. https://doi.org/10.1080/21655979.2019.1661694.
5. Ameer, Muhammad Haris, Khubab Shaker, Munir Ashraf, Mehmet Karahan, Yasir Nawab, Sheraz Ahmad, and Muhammad Ali Nasir. “Interdependence of Moisture, Mechanical Properties, and Hydrophobic Treatment of Jute Fibre-Reinforced Composite Materials.” The Journal of The Textile Institute 108, no. 10 (October 3, 2017): 1768–76. https://doi.org/10.1080/00405000.2017.1285201.
6. Liu, Yucheng, Jun Xie, Na Wu, Lidong Wang, Yunhai Ma, and Jin Tong. “Influence of Silane Treatment on the Mechanical, Tribological and Morphological Properties of Corn Stalk Fiber Reinforced Polymer Composites.” Tribology International 131 (March 2019): 398–405. https://doi.org/10.1016/j.triboint.2018.11.004.
7. Bindal, Amit, Satnam Singh, N. K. Batra, and Rajesh Khanna. “Development of Glass/Jute Fibers Reinforced Polyester Composite.” Indian Journal of Materials Science 2013 (November 11, 2013): 1–6. https://doi.org/10.1155/2013/675264.
8. Almeida, José Humberto Santos, Sandro Campos Amico, Edson Cocchieri Botelho, and Franco Dani Rico Amado. “Hybridization Effect on the Mechanical Properties of Curaua/Glass Fiber Composites.” Composites Part B: Engineering 55 (December 2013): 492–97. https://doi.org/10.1016/j.compositesb.2013.07.014.
9. Bindal, Amit, Satnam Singh, N. K. Batra, and Rajesh Khanna. “Development of Glass/Jute Fibers Reinforced Polyester Composite.” Indian Journal of Materials Science 2013 (November 11, 2013): 1–6. https://doi.org/10.1155/2013/675264.
10. Nejad, Ali Farokhi, Mohamad Yusuf Bin Salim, Seyed Saeid Rahimian Koloor, Stanislav Petrik, Mohd Yazid Yahya, Shukur Abu Hassan, and Mohd Kamal Mohd Shah. “Hybrid and Synthetic FRP Composites under Different Strain Rates: A Review.” Polymers 13, no. 19 (2021): 1–23. https://doi.org/10.3390/polym13193400.
11. Karthik, S, and V P Arunachalam. “Investigation on the Tensile and Flexural Behavior of Coconut Inflorescence Fiber Reinforced Unsaturated Polyester Resin Composites.” Materials Research Express 7, no. 1 (January 1, 2020): 015345. https://doi.org/10.1088/2053-1591/ab6c9d.
12. Javier-Astete, Rosario, Jorge Jimenez-Davalos, and Gaston Zolla. “Determination of Hemicellulose, Cellulose, Holocellulose and Lignin Content Using FTIR in Calycophyllum Spruceanum (Benth.) K. Schum. And Guazuma Crinita Lam.” PLoS ONE 16, no. 10 October (2021): 1–12. https://doi.org/10.1371/journal.pone.0256559.
13. Fuseya, Go, Satoshi Takeya, and Akihiro Hachikubo. “Temperature Effects on the C–H Symmetric Stretching Vibrational Frequencies of Guest Hydrocarbon Molecules in 5 12 , 5 12 6 2 and 5 12 6 4 Cages of SI and SII Clathrate Hydrates.” RSC Advances 10, no. 61 (2020): 37582–87. https://doi.org/10.1039/D0RA06668K.
14. Lu, Yongqiang, and Jan D. Miller. “Carboxyl Stretching Vibrations of Spontaneously Adsorbed and LB-Transferred Calcium Carboxylates as Determined by FTIR Internal Reflection Spectroscopy.” Journal of Colloid and Interface Science 256, no. 1 (December 2002): 41–52. https://doi.org/10.1006/jcis.2001.8112.
15. Zhuang, Jingshun, Mi Li, Yunqiao Pu, Arthur Jonas Ragauskas, and Chang Geun Yoo. “Observation of Potential Contaminants in Processed Biomass Using Fourier Transform Infrared Spectroscopy.” Applied Sciences (Switzerland) 10, no. 12 (2020): 1–13. https://doi.org/10.3390/app10124345.
16. NYQUIST, R. “Alkenes and Other Compounds Containing C=C Double Bonds.” In Interpreting Infrared, Raman, and Nuclear Magnetic Resonance Spectra, 55–91. Elsevier, 2001. https://doi.org/10.1016/B978-012523475-7/50168-6.