MICROSTRUCTURE EVOLUTION OF IN SITU COMPOSITE COATINGS FABRICATED BY LASER CLADDING WITH DIFFERENT POWERS

  • Youfeng Zhang School of Materials Engineering, Shanghai University of Engineering Science, No.333 Longteng Rd., Shanghai 201620, China
  • Guangyu Han School of Materials Engineering, Shanghai University of Engineering Science, No.333 Longteng Rd., Shanghai 201620, China
  • Shasha He School of Materials Engineering, Shanghai University of Engineering Science, No.333 Longteng Rd., Shanghai 201620, China
  • Wanwan Yang School of Materials Engineering, Shanghai University of Engineering Science, No.333 Longteng Rd., Shanghai 201620, China
Keywords: Laser cladding; Ti-6Al-4V alloy; Laser scanning power; Microstructure evolution; Composite coatings

Abstract

In situ reaction-synthesized TiB-reinforced titanium-matrix composite coatings were fabricated using the rapid, non-equilibrium synthesis technique of laser cladding. The Ti and B mixture was the original powders, while the Ti-matrix composite coatings enhanced with TiB were treated on a Ti-6Al-4V surface with different laser scan powers of 2.5 kW, 3.0 kW and 3.5 kW. The phase composition, microstructure evaluation, and microhardness of the cladding coatings were investigated by X-ray diffractometry (XRD), scanning electron microscopy (SEM) and microhardness. The composite coatings mainly consist of black fishbone-shaped -Ti dendrites and white needle-like TiB phases. The microstructure evolution from the top to the bottom of the coatings was investigated. The TiB reinforcement dispersed homogeneously in the composite coatings and a fine microstructure was obtained in a sample fabricated with a laser power of 3.0 kW. The microhardness of the cladding coatings fabricated by different powders was over 2-fold greater than that of the Ti-6Al-4V titanium alloy substrate and achieved a maximum average of 792.2 HV with the laser power of 3.0 kW. The microstructures and properties of the coatings were changed by adjusting of the laser cladding power. The effects of the laser scan power on the microstructure, hardness and friction and wear properties of the laser cladding coatings were investigated and discussed.

References

1 B. F. He, D. Y. Ma, F. Ma, K. W. Xu, Microstructures and wear properties of TiC coating produced by laser cladding on Ti-6Al-4V with TiC and carbon nanotube mixed powders, Ferroelectrics, 547 (2019) 1, 217–225, doi:10.1080/00150193.2019.1592502
2 Y. J. Zhai, X. B. Liu, S. J. Qiao, M. D. Wang, X. L. Lu, Y. G. Wang, Y. Chen, L. X. Ying, Characteristics of laser clad -Ti/TiC + (Ti,W)C1-x/Ti2SC + TiS composite coatings on TA2 titanium alloy, Optics and Laser Techology, 89 (2017), 97–107, doi:10.1016/ j.optlastec.2016.09.044
3 I. Sen, S. Tamirisakandala, D. B. Miracle, U. Ramamurty, Micro¬struc¬tural effects on the mechanical behavior of B-modified Ti-6Al-4V alloys, Acta Materialia, 55 (2007) 15, 4983–4993, doi:10.1016/j.actamat.2007.05.009
4 J. Li, Z. S. Yu, H. P. Wang, Wear behaviors of an (TiB+TiC)/Ti composite coating fabricated on Ti6Al4V by laser cladding, Thin Solid Films, 519 (2011) 15, 4804–4808, doi:10.1016/j.tsf.2011.01.034
5 R. L. Sun, D. Z. Yang, L. X. Guo, S. L. Dong, Laser cladding of Ti-6Al-4V alloy with TiC and TiC+NiCrBSi powders, Surface and Coatings Technology, 135 (2001) 2-3, 307–312, doi:10.1016/ S0257-8972(00)01082-3
6 Y. L. Yang, D. Zhang, W. Yan, Y. R. Zheng, Microstructure and wear properties of TiCN/Ti coatings on titanium alloy by laser cladding. Optics and Lasers in Engineering, 48 (2010) 1, 119–124, doi:10.1016/j.optlaseng.2009.08.003
7 Y. S. Tian, C. Z. Chen, S. T. Li, Q. H. Huo, Research progress on laser surface modification of titanium alloys, Applied Surface Science, 242 (2005) 1–2, 177–184, doi:10.1016/j.apsusc.2004.08.011
8 B. G. Guo, J. S. Zhou, S. T. Zhang, H. D. Zhou, Y. P. Pu, J. M. Chen, Microstructure and tribological properties of in situ synthesized TiN/Ti3Al intermetallic matrix composite coatings on titanium by laser cladding and laser nitriding, Materials Science and Engineering A-Structural Materials Properties Mirostructure and Processing, 480 (2008), 404–410, doi:10.1016/j.msea.2007.07.010
9 O. F. Ochonogor, C. Meacock, M. Abdulwahab, S. Pityana, A. P. I. Popoola, Effects of Ti and TiC ceramic powder on laser-cladded Ti–6Al–4V in situ intermetallic composite, Applied Surface Science, 263 (2012) 15, 591–596, doi:10.1016/j.apsusc.2012.09.114
10 Y. H. Lv, J. Li, Y. F. Tao, L. F. Hu, Oxidation behaviors of the TiNi/Ti2Ni matrix composite coatings with different contents of TaC addition fabricated on Ti6Al4V by laser cladding, Journal of Alloys and Compounds, 679 (2016) 15, 202–212, doi:10.1016/j.jallcom. 2016.04.037
11 M. Das, S. Bysakh, D. Basu, T. S. Sampath Kumar, V. Krishna, Balla S. Bose, A. Bandyopadhyay, Microstructure, mechanical and wear properties of laser processed SiC particle reinforced coatings on titanium, Surface and Coatings Technology, 205 (2011) 19, 4366–4373, doi:10.1016/j.surfcoat.2011.03.027
12 Z. Fan, A. P. Miodownik, L. Chandrasekaran, M. Ward-Close, The Young’s moduli of in situ Ti/TiB composites obtained by rapid solidification processing, Journal of Materials Science, 29 (1994), 1127–1134, doi:10.1007/BF00351442
13 L. F. Cai, Y. Z. Zhang, and L. K. Shi, Microstructure and formation mechanism of titanium matrix composites coatings on Ti-6Al-4V by laser cladding, Rare Metals, 26 (2007) 5, 342–346, doi:10.1016/ S1001-0521(07)60226-5
14 F. Wang, J. Mei, X. H. Wu, Direct laser fabrication of Ti6Al4V/TiB, Journal of Materials Processing Technology, 195 (2008) 1–3, 321–326, doi:10.1016/j.jmatprotec.2007.05.024
15 D. R. Ni, L. Geng, J. Zhang, Z. Z. Zheng, Effect of B4C particle size on microstructure of in situ titanium matrix composites prepared by reactive processing of Ti–B4C system, Scripta Materialia, 55 (2006) 5, 429–432, doi:10.1016/j.scriptamat.2006.05.024
16 P. Chandrasekar, V. Balusamy, K. S. Ravi Chandranb, H. Kumar, Laser surface hardening of titanium–titanium boride (Ti-TiB) metal matrix composite, Scripta Materialia, 56 (2007) 7, 641–644, doi:10.1016/j.scriptamat.2006.11.035
17 V. Ocelik, D. Matthews, J. Th. M. De Hosson, Sliding wear resistance of metal matrix composite layers prepared by high power laser, Surface and Coatings Technology, 197 (2005) 2–3, 303–315, doi:10.1016/j.surfcoat.2004.09.003
18 J. C. Oh, D. K. Choo, S. Lee, Microstructural modification and hardness improvement of titanium-base surface-alloyed materials fabricated by high-energy electron beam irradiation, Surface and Coatings Technology, 127 (2000) 1, 76–85, doi:10.1016/S0257-¬8972(99) 00664-7
19 Y. S. Tian, Q. Y. Zhang, D. Y. Wang, C. Z. Chen, Analysis of the Growth Morphology of TiB and the Microstructure Refinement of the Coatings Fabricated on Ti-6Al-4V by Laser Boronizing, Crystal Growth & Design, 8 (2008) 2, 700–703, doi:10.1021/cg0608099
20 R. Banerjee, A. Genc, P.C. Collins, H. L. Fraser, Comparison of microstructural evolution in laser-deposited and arc-melted In-Situ Ti-TiB, Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science, 35 (2004), 2143–2152, doi:10.1007/ s11661-004-0162-0
Published
2021-06-02
How to Cite
1.
Zhang Y, Han G, He S, Yang W. MICROSTRUCTURE EVOLUTION OF IN SITU COMPOSITE COATINGS FABRICATED BY LASER CLADDING WITH DIFFERENT POWERS. MatTech [Internet]. 2021Jun.2 [cited 2025Jan.19];55(3):419–425. Available from: https://mater-tehnol.si/index.php/MatTech/article/view/181