EXPERIMENTAL INVESTIGATION ON TRIBOLOGY AND MECHANICAL CHARACTERISTICS OF FUNCTIONALIZED GRAPHENE AND MWCNTs REINFORCED EPOXY HYBRID NANOCOMPOSITES
Abstract
The development of epoxy-based hybrid nanocomposites reinforced with functionalized graphene and multi-walled carbon nanotubes (MWCNTs) has emerged as a promising strategy to enhance structural performance under combined mechanical and tribological characteristics. In this study, the tribological and mechanical characteristics of epoxy and its hybrid nanocomposites (EGpCn1–EGpCn5) was systematically evaluated under different loads, obtaining results that indicated a significant improvement in the wear resistance of the optimized formulations. Among all compositions, EGpCn3 demonstrated superior wear performance, exhibiting considerably lower material loss, smoother worn surfaces as well as evidence of nanofiller bridging and thin-film formation, which acted as protective layers against severe abrasive damage. Conversely, EGpCn5 revealed deep grooves, nanofiller bundles and pull-out regions, indicating poor dispersion and leading to accelerated wear degradation. Beyond tribological performance, the tensile properties of the hybrid nanocomposites also exhibited noteworthy enhancements, with EGpCn3 achieving the highest tensile strength of 69.12 MPa, corresponding to an almost 88 % increase over epoxy (36.71 MPa). This remarkable improvement can be attributed to strong interfacial adhesion, effective stress transfer and restricted crack propagation facilitated by the uniform graphene–MWCNT network. However, EGpCn5 again showed considerably lower tensile strength (27.12 MPa), where large voids, agglomeration and stepped fracture morphology confirmed the detrimental effect of poor nanofiller dispersion. Morphological examinations, using SEM, further demonstrated that the synergistic interaction of graphene and MWCNTs provided superior reinforcement by bridging microcracks, dissipating energy and enhancing load bearing capacity under both static and dynamic conditions.
References
2 A.K. Geim, K.S. Novoselov, Nature Materials 6(3), 183–191 (2007).
3 E.T. Thostenson, Z. Ren, T.-W. Chou, Composites Science and Technology 61(13), 1899–1912 (2001): https://doi.org/10.1016/S0266-3538(01)00094-X
4 F.H. Gojny, M.H.G. Wichmann, U. Köpke, B. Fiedler, K. Schulte, Composites Science and Technology 64(15), 2363–2371 (2004): https://doi.org/10.1016/j.compscitech.2004.04.002
5 H. Kim, A.A. Abdala, C.W. Macosko, Macromolecules 43(16), 6515–6530 (2010): https://doi.org/10.1021/ma100572e
6 M.A. Rafiee, J. Rafiee, Z. Wang, H. Song, Z.-Z. Yu, N. Koratkar, ACS Nano 3(12), 3884–3890 (2009): https://doi.org/10.1021/nn9010472
7 S.-Y. Yang, W.-N. Lin, Y.-L. Huang et al., Carbon 49(3), 793–803 (2011): https://doi.org/10.1016/j.carbon.2010.10.014.
8 W. Li, A. Dichiara, J. Bai, Composites Science and Technology 74, 221–227 (2013): https://doi.org/10.1016/j.compscitech.2012.11.015
9 S. Chatterjee, F. Nafezarefi, N.H. Tai, L. Schlagenhauf, F.A. Nüesch, B.T.T. Chu, Carbon 50(14), 5380–5386 (2012): https://doi.org/10.1016/j.carbon.2012.07.021
10 M.A. Rafiee, J. Rafiee, Z. Wang, ACS Nano 3(12), 3884–3890 (2009): 10.1021/nn9010472
11 J. Zhu, H. Peng, F. Rodriguez-Macías et al., Advanced Functional Materials 14(7), 643–648 (2004): https://doi.org/10.1002/adfm.200305162
12 F.H. Gojny, M.H.G. Wichmann, B. Fiedler, K. Schulte, Composites Part A: Applied Science and Manufacturing 36(11), 1525–1535 (2005): https://doi.org/10.1016/j.compositesa.2005.02.007
13 Y. Xu, W. Lu, Applied Surface Science 362, 43–50 (2016): https://doi.org/10.1016/j.apsusc.2015.11.061
14 L.C. Zhang, I. Zarudi, K.Q. Xiao, Wear 261(7–8), 806–811 (2006): https://doi.org/10.1016/j.wear.2006.01.033
15 P. N. Karthikeyan, B. G. Babu, K. Siva, C. Sabarinathan, Digest Journal of Nanomaterials and Biostructures, 11(2), 625-632 (2016)
16 G. Mittal, V. Dhand, K.Y. Rhee, S.-J. Park, W.R. Lee, Journal of Industrial and Engineering Chemistry 21, 11–25 (2015): https://doi.org/10.1016/j.jiec.2014.03.022.