A MODIFYING GO AND DOPING IT IN WATERBORNE ACRYLIC COATINGS TO ENHANCE THEIR MECHANICAL PERFORMANCE AND CORROSION PROTECTION
Keywords:
Hydroxyacrylic acid dispersion coating; Modified graphene oxide; Grafting; Mechanical properties; Anti-corrosion properties
Abstract
With the development of science and technology and the ever-increasing focus of the environmental protection, waterborne acrylic resin based coating has been commonly used in a wide range of applications due to its high flexibility and good UV resistance. Continuous attempts have been extensively carried out to improve its corrosion resistance and mechanical properties through doping of different nanomaterials. In this study, Functionalized Graphene Oxide (FGO) nanosheets covalently bonded to hydroxylated acrylic resin was introduced into the Hydroxyacrylic Acid Dispersion (HAD) matrix to enhance the performance. To study the effect of grafted hydroxylated acrylic resin on morphology and properties of GO nanosheets, the GO and FGO nanosheets have been systematically characterized with various testing methods, such as FTIR, field emission-scanning electron microscopy (FE-SEM), transmission electron microscope (TEM), Raman spectroscopy, X-ray diffraction (XRD) analysis, UV–vis analysis, and thermogravimetric analysis (TGA). The morphology, physical–mechanical, and anti-corrosion properties of the HAD coatings doped with GO and FGO nanosheets have been compared. The results confirmed that FGO’s dispersion behavior in the HAD matrix has been improved after modifification with the hydroxylated acrylic resin, and the interfacial bonds between the HAD-FGO nanosheets have been significantly enhanced.
References
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[2]Li W, Qiu Z, Tebyetekerwa M, et al. “Preparation of silica/polymer nanocomposites with aggregation-induced emission properties as fluorescent responsive coatings”. Prog. Org. Coat.,127(2019)8-15.
[3]Li W, Yao W, Tebyetekerwa M, et al. “Materials interaction in aggregation-induced emission (AIE)-based fluorescent resin for smart coatings” J. Mater. Chem. C, 6(2018)12849-12857.
[4] Li W, Huang D, Xing X Y, et al. “Study the Factors Affecting the Performance of Organic–Inorganic Hybrid Coatings” J. Appl. Polym. Sci., 131(21)(2015)41010.
[5] Zhang F , Liu W , Liang L , et al. “The effect of functional graphene oxide nanoparticles on corrosion resistance of waterborne polyurethane”, Colloids Surfaces A, 591(2020)124565.
[6] Ramezanzadeh B , Niroumandrad S , Ahmadi A , et al. “Enhancement of barrier and corrosion protection performance of an epoxy coating through wet transfer of amino functionalized graphene oxide”, Corros Sci, 103 (2016)283-304.
[4]Wan Y J , Gong L X , Tang L C , et al. “Mechanical properties of epoxy composites filled with
silane-functionalized graphene oxide”,Composites Part A, 64(2014)79-89.
[5]Haghdadeh P, Mehdi G., Bahram R. “The role of functionalized graphene oxide on the mechanical and anti-corrosion properties of polyurethane coating”, J Taiwan Inst Chem E, 000(2018)1-14.
[6]Li H , Wang J, Yang J, et al. “Water-based fluorescent paint: Presenting a novel approach to study and solve the aggregation caused quench (ACQ) effect in traditional fluorescent materials”, Progress in Organic Coatings, 143(2020)1-9.
[7]Kim, M.; Kim, Y.; Baeck, S.H. et al “Effect of surface treatment of graphene nanoplatelets for improvement of thermal and electrical properties of epoxy composites.” Carbon Lett.,16(2015)34–40.
[8]Du Y , Li N , Zhang T L, et al. “Reduced Graphene Oxide Coating with Anticorrosion and Electrochemical Property-Enhancing Effects Applied in Hydrogen Storage System” ACS Appl Mater Inter,9(2017)28980-28989.
[12] Ramezanzadeh B., Ghasemi E., Mandavian M., et al. “Characterization of covalently-grafted polyisocyanate chains onto graphene oxide for polyurethane composites with improved mechanical properties”,Chem Eng J, 281(2015)869-883.
[13] Ma Y., Di H., Yu Z.,et.al Applied Surface Science, “Fabrication of silica-decorated graphene oxide nanohybrids and the properties of composite epoxy coatings research”, 360(2016)936-945.
[14] Schniepp HC, Li JL, McAllister MJ, Sai H, Herrera-Alonso M, Adamson DH, et al.”Functionalized single graphene sheets derived from splitting graphite oxide”. J Phys Chem B ;110(17)(2006)8535–8539.
[15] Liao K.H. , Qian Y., Macosko C.W.et al. Ultralow percolation graphene/polyurethane acrylate nanocomposites, Polymer,,53(17)(2012)3756-3761.
[16] Hu L.,Jiang P., Zhang P., Bian G., et al. “Amine-graphene oxide/waterborne polyurethane nanocomposites: effects of different amine modifiers on physical properties” J. Mater. Sci. ,51(18)(2016)8296-8309.
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[19] Ramezanzadeh B, Mohamadzadeh Moghadam MH, Shohani N, et al. “Effects of highly crystalline and conductive polyaniline/graphene oxide composites on the corrosion protection performance of a zinc-rich epoxy coating”. Chem Eng J 320(2017)363-375.
[20] Hou D, Han M., Muhammad Y., Liu Y., et al “Performance evaluation of modified asphalt based trackless tack coat materials, Constr. Build. Mater. 165(2018)385–394 .
[21] Yadav S.K., ChoJ .W., “Functionalized graphene nanoplatelets for enhanced mechanical and thermal properties of polyurethane nanocomposites,” Appl. Surf. Sci. 266(2013)360–367.
[22] W. Li, D. Huang, J. Wang, et al., “A novel stimuli-responsive fluorescent elastomer based on AIE mechanism”, Polym. Chem. 6(2015)8194-8202 .
[23] Sari MG, Shamshiri M, Ramezanzadeh B. “Fabricating an epoxy composite coating with enhanced corrosion resistance through impregnation of functionalized graphene oxide-co-montmorillonite nanoplatelet”. Corros Sci 129,(2017)38–53.
[24] Liang J, Huang Y, Zhang L, Wang Y, Ma Y, Guo T, et al. “Molecular-Level Dispersion of Graphene into Poly(vinyl alcohol) and Effective Reinforcement of their Nanocomposites”. Adv Funct Mater, 19(14),(2009)2297-2302.
[25] Hu Y., Liu C., Shang Q., Zhou Y., “Synthesis and characterization of novel renewable castor oil-based UV-curable polyfunctional polyurethane acrylate”, J. Coat. Technol. Res.(2017)1–9 .
[24] Pottathara Y.B., Thomas S., Kalarikkal N., T. et al, “UV-induced reduction of graphene oxide in cellulose nanofibril composites”, New J. Chem. 43 (2019)681–688.
[25] Chen W.,Liu P.,Min L.,Zhou Y., Liu Y.,Wang Q.,Duan W. “Non-covalently functionalized graphene oxide-based coating to enhance thermal stability and flameretardancy of PVA film”, Nano-micro Lett. 10, (2018)39.
[26] Parhizkar N., Shahrabi T., Ramezanzadeh B., “A new approach for enhancement of the corrosion protection properties and interfacial adhesion bonds between the epoxy coating and steel substrate through surface treatment by covalently modified amino functionalized graphene oxide film”, Corros. Sci. 123,(2017) 55–75 .
[27] Vignesh R.B., Balaji J., Sethuraman M.G., Surface modification, characterization and corrosion protection of 1,3-diphenylthiourea doped sol-gel coating on aluminium, Prog. Org. Coat. 111,(2017)112-123 .
[28] Zheng H., Guo M., Shao Y., Wang Y., Liu B., Meng G., Graphene oxide poly(urea-formaldehyde) composites for corrosion protection of mild steel, Corros. Sci. 139 (2018)1-12 .
[29]Li W, Huang D, Xing X Y, et al. Study the factors affecting the performance of organic–inorganic hybrid coatings J. Appl Polym Sci,131(21),(2015)41010.
[30]Yousefi N., Moazzami Gudarzi M., Zheng Q., Lin X., Shen X.,et al “Highly aligned, ultralarge-size reduced graphene oxide/polyurethane nanocomposites: mechanical properties and moisture permeability”,Composites Part A: Appl. Sci. Manuf. 49(2013).42–50
[31]Li W., Shen W., Yao W., et al., “A novel acrylate-PDMS composite latex with controlled phase compatibility prepared by emulsion polymerization”, J. Coat. Technol. Res. 1(2017)1–11.
[32]Li Q., Liu C., Wen J., Wu Y., Shan Y., Liao J., “The design, mechanism and biomedical application of self-healing hydrogels”, Chin. Chem. Lett. 28(2017)1857–1874 .
[33] Tang L-C, Wan Y-J, Yan D, Pei Y-B, Zhao L, Li Y-B, Wu L-B, Jiang J-X, Lai G-Q. The effect of graphene dispersion on the mechanical properties of graphene/epoxy composites. Carbon, 60(2013)16–27.
Published
2021-05-31
How to Cite
1.
Wang X, Xie Y, Cong W, Li Z, Xu Z, Yan H, Gui T, Li W. A MODIFYING GO AND DOPING IT IN WATERBORNE ACRYLIC COATINGS TO ENHANCE THEIR MECHANICAL PERFORMANCE AND CORROSION PROTECTION. MatTech [Internet]. 2021May31 [cited 2025Jan.19];55(3):401–409. Available from: https://mater-tehnol.si/index.php/MatTech/article/view/10
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